New light-emitting poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]}
Identifieur interne : 002930 ( Main/Repository ); précédent : 002929; suivant : 002931New light-emitting poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]}
Auteurs : RBID : Pascal:12-0090750Descripteurs français
- Pascal (Inist)
- Copolymère alterné, Polycondensation solution, Stabilité thermique, Fluorescence, Photoluminescence, Dispositif électroluminescent, Dérivé du naphtalène, Copolymère conjugué, Electroluminescence, Caractéristique courant tension, Fluorène dérivé copolymère, Réaction Horner Emmons, Composé soluble, Préparation, Etude expérimentale, Polymère conducteur, Propriété thermique, Propriété optique, Fluorénylènevinylène dérivé copolymère, Fluorénylènevinylène(9,9-dioctyl) copolymère, Naphtylènevinylène(2,6dioctyloxy) copolymère, Naphtalène dérivé copolymère.
English descriptors
- KwdEn :
- Alternating copolymer, Conducting polymers, Conjugated copolymer, Electroluminescence, Electroluminescent device, Experimental study, Fluorene derivative copolymer, Fluorescence, Horner Emmons reaction, Naphthalene derivatives, Optical properties, Photoluminescence, Preparation, Soluble compound, Solution polycondensation, Thermal properties, Thermal stability, Voltage current curve.
Abstract
A new conjugated light-emitting AB copolymer containing alternating fluorene and naphthalene units, poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]) (PFV-alt-PNV), was synthesized via Horner-Emmons polymerization. The polymer is completely soluble in common organic solvents and exhibits good thermal stability up to 400°C. UV-visible, fluorescence and photoluminescence measurements of the copolymer show peak maxima at 427, 500 and 526 nm, respectively. A light-emitting device containing the new polymer was fabricated using a simple indium tin oxide configuration: (ITO)/PEDOT:PSS/PFV-alt-PNV/Al. Measurements of current versus electric field were carried out, with an onset of light emission occurring at 2.5 V. The electroluminescence brightness was observed to reach a maximum of 5000 cd m-2.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">New light-emitting poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]}</title><author><name sortKey="Anuragudom, Piched" uniqKey="Anuragudom P">Piched Anuragudom</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Faculty of Science and the Center for Innovation in Chemistry (PERCH-CIC), Chiang Mai University</s1><s2>Chiang Mai 50200</s2><s3>THA</s3><sZ>1 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Thaïlande</country><wicri:noRegion>Chiang Mai 50200</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Department of Chemistry, Faculty of Liberal Arts and Science, Kasetsart University, Kamphaeng Saen Campus, Kamphaeng Saen</s1><s2>Nakhon Pathom 73140</s2><s3>THA</s3><sZ>1 aut.</sZ></inist:fA14><country>Thaïlande</country><wicri:noRegion>Nakhon Pathom 73140</wicri:noRegion></affiliation></author><author><name sortKey="Ei Daye, Jad" uniqKey="Ei Daye J">Jad Ei-Daye</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Department of Chemistry and the Texas Center for Superconductivity, University of Houston, 4800 Calhoun Road</s1><s2>Houston, TX 77204-5003</s2><s3>USA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>États-Unis</country><wicri:noRegion>Houston, TX 77204-5003</wicri:noRegion></affiliation></author><author><name sortKey="Chinwangso, Pawilai" uniqKey="Chinwangso P">Pawilai Chinwangso</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Department of Chemistry and the Texas Center for Superconductivity, University of Houston, 4800 Calhoun Road</s1><s2>Houston, TX 77204-5003</s2><s3>USA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>États-Unis</country><wicri:noRegion>Houston, TX 77204-5003</wicri:noRegion></affiliation></author><author><name sortKey="Advincula, Rigoberto C" uniqKey="Advincula R">Rigoberto C. Advincula</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Department of Chemistry and the Texas Center for Superconductivity, University of Houston, 4800 Calhoun Road</s1><s2>Houston, TX 77204-5003</s2><s3>USA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>États-Unis</country><wicri:noRegion>Houston, TX 77204-5003</wicri:noRegion></affiliation></author><author><name sortKey="Phanichphant, Sukon" uniqKey="Phanichphant S">Sukon Phanichphant</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Faculty of Science and the Center for Innovation in Chemistry (PERCH-CIC), Chiang Mai University</s1><s2>Chiang Mai 50200</s2><s3>THA</s3><sZ>1 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Thaïlande</country><wicri:noRegion>Chiang Mai 50200</wicri:noRegion></affiliation></author><author><name sortKey="Lee, T Randall" uniqKey="Lee T">T. Randall Lee</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Department of Chemistry and the Texas Center for Superconductivity, University of Houston, 4800 Calhoun Road</s1><s2>Houston, TX 77204-5003</s2><s3>USA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>États-Unis</country><wicri:noRegion>Houston, TX 77204-5003</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">12-0090750</idno><date when="2011">2011</date><idno type="stanalyst">PASCAL 12-0090750 INIST</idno><idno type="RBID">Pascal:12-0090750</idno><idno type="wicri:Area/Main/Corpus">002186</idno><idno type="wicri:Area/Main/Repository">002930</idno></publicationStmt><seriesStmt><idno type="ISSN">0959-8103</idno><title level="j" type="abbreviated">Polym. int.</title><title level="j" type="main">Polymer international</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Alternating copolymer</term><term>Conducting polymers</term><term>Conjugated copolymer</term><term>Electroluminescence</term><term>Electroluminescent device</term><term>Experimental study</term><term>Fluorene derivative copolymer</term><term>Fluorescence</term><term>Horner Emmons reaction</term><term>Naphthalene derivatives</term><term>Optical properties</term><term>Photoluminescence</term><term>Preparation</term><term>Soluble compound</term><term>Solution polycondensation</term><term>Thermal properties</term><term>Thermal stability</term><term>Voltage current curve</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Copolymère alterné</term><term>Polycondensation solution</term><term>Stabilité thermique</term><term>Fluorescence</term><term>Photoluminescence</term><term>Dispositif électroluminescent</term><term>Dérivé du naphtalène</term><term>Copolymère conjugué</term><term>Electroluminescence</term><term>Caractéristique courant tension</term><term>Fluorène dérivé copolymère</term><term>Réaction Horner Emmons</term><term>Composé soluble</term><term>Préparation</term><term>Etude expérimentale</term><term>Polymère conducteur</term><term>Propriété thermique</term><term>Propriété optique</term><term>Fluorénylènevinylène dérivé copolymère</term><term>Fluorénylènevinylène(9,9-dioctyl) copolymère</term><term>Naphtylènevinylène(2,6dioctyloxy) copolymère</term><term>Naphtalène dérivé copolymère</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A new conjugated light-emitting AB copolymer containing alternating fluorene and naphthalene units, poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]) (PFV-alt-PNV), was synthesized via Horner-Emmons polymerization. The polymer is completely soluble in common organic solvents and exhibits good thermal stability up to 400°C. UV-visible, fluorescence and photoluminescence measurements of the copolymer show peak maxima at 427, 500 and 526 nm, respectively. A light-emitting device containing the new polymer was fabricated using a simple indium tin oxide configuration: (ITO)/PEDOT:PSS/PFV-alt-PNV/Al. Measurements of current versus electric field were carried out, with an onset of light emission occurring at 2.5 V. The electroluminescence brightness was observed to reach a maximum of 5000 cd m<sup>-2</sup>.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0959-8103</s0></fA01><fA03 i2="1"><s0>Polym. int.</s0></fA03><fA05><s2>60</s2></fA05><fA06><s2>4</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>New light-emitting poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]}</s1></fA08><fA11 i1="01" i2="1"><s1>ANURAGUDOM (Piched)</s1></fA11><fA11 i1="02" i2="1"><s1>EI-DAYE (Jad)</s1></fA11><fA11 i1="03" i2="1"><s1>CHINWANGSO (Pawilai)</s1></fA11><fA11 i1="04" i2="1"><s1>ADVINCULA (Rigoberto C.)</s1></fA11><fA11 i1="05" i2="1"><s1>PHANICHPHANT (Sukon)</s1></fA11><fA11 i1="06" i2="1"><s1>LEE (T. Randall)</s1></fA11><fA14 i1="01"><s1>Department of Chemistry, Faculty of Science and the Center for Innovation in Chemistry (PERCH-CIC), Chiang Mai University</s1><s2>Chiang Mai 50200</s2><s3>THA</s3><sZ>1 aut.</sZ><sZ>5 aut.</sZ></fA14><fA14 i1="02"><s1>Department of Chemistry, Faculty of Liberal Arts and Science, Kasetsart University, Kamphaeng Saen Campus, Kamphaeng Saen</s1><s2>Nakhon Pathom 73140</s2><s3>THA</s3><sZ>1 aut.</sZ></fA14><fA14 i1="03"><s1>Department of Chemistry and the Texas Center for Superconductivity, University of Houston, 4800 Calhoun Road</s1><s2>Houston, TX 77204-5003</s2><s3>USA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>6 aut.</sZ></fA14><fA20><s1>660-665</s1></fA20><fA21><s1>2011</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>14717</s2><s5>354000192847370190</s5></fA43><fA44><s0>0000</s0><s1>© 2012 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>45 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>12-0090750</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Polymer international</s0></fA64><fA66 i1="01"><s0>GBR</s0></fA66><fC01 i1="01" l="ENG"><s0>A new conjugated light-emitting AB copolymer containing alternating fluorene and naphthalene units, poly{(9,9-di-n-octylfluorenediyl vinylene)-alt-[1,5-(2,6-dioctyloxy)naphthalene vinylene]) (PFV-alt-PNV), was synthesized via Horner-Emmons polymerization. The polymer is completely soluble in common organic solvents and exhibits good thermal stability up to 400°C. UV-visible, fluorescence and photoluminescence measurements of the copolymer show peak maxima at 427, 500 and 526 nm, respectively. A light-emitting device containing the new polymer was fabricated using a simple indium tin oxide configuration: (ITO)/PEDOT:PSS/PFV-alt-PNV/Al. Measurements of current versus electric field were carried out, with an onset of light emission occurring at 2.5 V. The electroluminescence brightness was observed to reach a maximum of 5000 cd m<sup>-2</sup>.</s0></fC01><fC02 i1="01" i2="X"><s0>001D09D02E</s0></fC02><fC02 i1="02" i2="X"><s0>001D03F15</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Copolymère alterné</s0><s2>NK</s2><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Alternating copolymer</s0><s2>NK</s2><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Copolímero alternado</s0><s2>NK</s2><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Polycondensation solution</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Solution polycondensation</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Policondensación solución</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Stabilité thermique</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Thermal stability</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Estabilidad térmica</s0><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Fluorescence</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Fluorescence</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Fluorescencia</s0><s5>04</s5></fC03><fC03 i1="05" i2="X" l="FRE"><s0>Photoluminescence</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="ENG"><s0>Photoluminescence</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="SPA"><s0>Fotoluminiscencia</s0><s5>05</s5></fC03><fC03 i1="06" i2="X" l="FRE"><s0>Dispositif électroluminescent</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="ENG"><s0>Electroluminescent device</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="SPA"><s0>Dispositivo electroluminiscente</s0><s5>06</s5></fC03><fC03 i1="07" i2="X" l="FRE"><s0>Dérivé du naphtalène</s0><s1>ENT</s1><s5>07</s5></fC03><fC03 i1="07" i2="X" l="ENG"><s0>Naphthalene derivatives</s0><s1>ENT</s1><s5>07</s5></fC03><fC03 i1="07" i2="X" l="SPA"><s0>Naftaleno derivado</s0><s1>ENT</s1><s5>07</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Copolymère conjugué</s0><s2>NK</s2><s5>08</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Conjugated copolymer</s0><s2>NK</s2><s5>08</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Copolímero conjugado</s0><s2>NK</s2><s5>08</s5></fC03><fC03 i1="09" i2="X" l="FRE"><s0>Electroluminescence</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="ENG"><s0>Electroluminescence</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="SPA"><s0>Electroluminiscencia</s0><s5>09</s5></fC03><fC03 i1="10" i2="X" l="FRE"><s0>Caractéristique courant tension</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="ENG"><s0>Voltage current curve</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="SPA"><s0>Característica corriente tensión</s0><s5>10</s5></fC03><fC03 i1="11" i2="X" l="FRE"><s0>Fluorène dérivé copolymère</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="ENG"><s0>Fluorene derivative copolymer</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="SPA"><s0>Fluoreno derivado copolímero</s0><s5>11</s5></fC03><fC03 i1="12" i2="X" l="FRE"><s0>Réaction Horner Emmons</s0><s5>12</s5></fC03><fC03 i1="12" i2="X" l="ENG"><s0>Horner Emmons reaction</s0><s5>12</s5></fC03><fC03 i1="12" i2="X" l="SPA"><s0>Reacción Horner Emmons</s0><s5>12</s5></fC03><fC03 i1="13" i2="X" l="FRE"><s0>Composé soluble</s0><s5>13</s5></fC03><fC03 i1="13" i2="X" l="ENG"><s0>Soluble compound</s0><s5>13</s5></fC03><fC03 i1="13" i2="X" l="SPA"><s0>Compuesto soluble</s0><s5>13</s5></fC03><fC03 i1="14" i2="X" l="FRE"><s0>Préparation</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="ENG"><s0>Preparation</s0><s5>14</s5></fC03><fC03 i1="14" i2="X" l="SPA"><s0>Preparación</s0><s5>14</s5></fC03><fC03 i1="15" i2="X" l="FRE"><s0>Etude expérimentale</s0><s5>15</s5></fC03><fC03 i1="15" i2="X" l="ENG"><s0>Experimental study</s0><s5>15</s5></fC03><fC03 i1="15" i2="X" l="SPA"><s0>Estudio experimental</s0><s5>15</s5></fC03><fC03 i1="16" i2="3" l="FRE"><s0>Polymère conducteur</s0><s5>31</s5></fC03><fC03 i1="16" i2="3" l="ENG"><s0>Conducting polymers</s0><s5>31</s5></fC03><fC03 i1="17" i2="X" l="FRE"><s0>Propriété thermique</s0><s5>32</s5></fC03><fC03 i1="17" i2="X" l="ENG"><s0>Thermal properties</s0><s5>32</s5></fC03><fC03 i1="17" i2="X" l="SPA"><s0>Propiedad térmica</s0><s5>32</s5></fC03><fC03 i1="18" i2="X" l="FRE"><s0>Propriété optique</s0><s5>33</s5></fC03><fC03 i1="18" i2="X" l="ENG"><s0>Optical properties</s0><s5>33</s5></fC03><fC03 i1="18" i2="X" l="SPA"><s0>Propiedad óptica</s0><s5>33</s5></fC03><fC03 i1="19" i2="X" l="FRE"><s0>Fluorénylènevinylène dérivé copolymère</s0><s2>NK</s2><s4>INC</s4><s5>41</s5></fC03><fC03 i1="20" i2="X" l="FRE"><s0>Fluorénylènevinylène(9,9-dioctyl) copolymère</s0><s2>NK</s2><s4>INC</s4><s5>42</s5></fC03><fC03 i1="21" i2="X" l="FRE"><s0>Naphtylènevinylène(2,6dioctyloxy) copolymère</s0><s4>INC</s4><s5>43</s5></fC03><fC03 i1="22" i2="X" l="FRE"><s0>Naphtalène dérivé copolymère</s0><s2>NK</s2><s4>INC</s4><s5>44</s5></fC03><fN21><s1>072</s1></fN21></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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